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Biomed Res Int
2018 Jan 01;2018:7921247. doi: 10.1155/2018/7921247.
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Effect of Camphorquinone Concentration in Physical-Mechanical Properties of Experimental Flowable Resin Composites.
Maciel DDSA
,
Caires-Filho AB
,
Fernandez-Garcia M
,
Anauate-Netto C
,
Alonso RCB
.
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The aim of this study was to evaluate the effect of camphorquinone concentration in physical-mechanical properties of experimental flowable composites in order to find the concentration that results in maximum conversion, balanced mechanical strength, and minimum shrinkage stress. Model composites based on BISGMA/TEGDMA with 70% wt filler loading were prepared containing different concentrations of camphorquinone (CQ) on resin matrix (0.25%, 0.50%, 1%, 1.50%, and 2% by weight). Degree of conversion was determined by FTIR. Surface hardness was assessed before and after 24 h ethanol storage and softening rate was determined. Depth of cure was determined by Knoop hardness evaluation at different depths. Color was assessed by reflectance spectrophotometer, employing the CIE-Lab system. Flexural strength and elastic modulus were determined by a three-point bending test. Shrinkage stress was determined in a Universal Testing Machine in a high compliance system. Data were submitted to ANOVA and Tukey''s test (α = 0.05). The increase in CQ concentration caused a significant increase on flexural strength and luminosity of composites. Surface hardness was not affected by the concentration of CQ. Composite containing 0.25% wt CQ showed lower elastic modulus and shrinkage stress when compared to others. Depth of cure was 3 mm for composite containing 1% CQ and 2 mm for the other tested composites. Degree of conversion was inversely correlated with softening rate and directly correlated with elastic modulus and shrinkage stress. In conclusion, CQ concentration affects polymerization characteristics and mechanical strength of composites. The concentration of CQ in flowable composite for optimized polymerization and properties was 1% wt of the resin matrix, which allows adequate balance among degree of conversion, depth of cure, mechanical properties, and color characteristics of these materials.
Figure 1. Depth of cure of experimental composites according to concentration of CQ. Black line at 0.8 KHN ratio shows the composites with acceptable ratio. Only the composite containing 1% CQ (yellow line) showed KHN ratio higher than 0.8 at 3 mm depth.
Figure 2. Analysis of linear correlation between concentration of CQ and degree of conversion versus softening rate, surface hardness, flexural strength, elastic modulus, and shrinkage stress.
Figure 3. Analysis of linear correlation between concentration of photoinitiators and color parameters (yellowing and luminosity).
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