ECB-ART-45748
Chem Commun (Camb)
2017 Sep 25;5375:10358-10361. doi: 10.1039/c7cc06116a.
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A nickel-phyllosilicate core-echinus catalyst via a green and base additive free hydrothermal approach for hydrogenation reactions.
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We report a new hydrothermal and basic-additive free process for synthesizing a core(single-crystalline HBEA zeolite)-echinus(nickel phyllosilicate) catalyst, which exhibits excellent reactivity and stability for hydrogenation reactions. Desilication and dealumination processes generate substantial SiO32- ions and exposed Si-OH groups to form nickel phyllosilicate on the external and internal surfaces of zeolite.
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