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Echinobase
ECB-ART-36728
J Nat Prod 1997 Aug 01;608:817-9. doi: 10.1021/np9701541.
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Structure of eximisoside A, a novel triterpene glycoside from the Far-Eastern sea cucumber psolus eximius.

Kalinin VI , Avilov SA , Kalinina EY , Korolkova OG , Kalinovsky AI , Stonik VA , Riguera R , Jiménez C .


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The new triterpene saponin eximisoside A (1) has been isolated from the Far-Eastern sea cucumber Psolus eximius and its structure elucidated by 1D and 2D NMR (13C, 1H, 1H-1H COSY, HMQC, and NOESY spectra), and FABMS studies. The structural features of eximisoside A (1) are the rare presence of a 23 double bond in the aglycon and the absence of quinovose, typically found in the oligosaccharide chain of holothurian glycosides.

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Genes referenced: LOC100887844